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19 Dec 2000

Nagase's newly developed Master Batch, functions as anti-microbial, anti-mold and ant-algae at the same time


Nagase's joint development with subsidiary company Nagase Chemicals has successfully resulted in a Master Batch compounding new organic agent that displayed ability in anti-microbial, anti-mold and anti-algae simultaneously. This owes to their know-how of the sophisticated formulation in compounding the two components - high safety powder and liquid, which was once considered extremely difficult to formulate with emulsification technology.

The new master batch branded "Denimas CP8" is a transparent PVC pellet compounded by adding organic nitrogen-sulfur liquid to zinc pyrithione powder. Zinc pyrithione has long been used in skin-contacting ingredients for shampoos and others, while organic nitrogen-sulfur in ingredients shows no irritation to skin as well. Thus both are identified as highly safe in results of various tests. The formulation also contains a plasticizer DINP, with low skin irritation.

It is generally said that organic substance shows better anti-mold property while inorganic substance shows superior anti-microbial-fungicidal property when used in plastics. Suppliers are marketing these agents promoting the advantageous feature of each of these organic and inorganic substances. On the other hand, there has been a strong demand in the industry for a pre-made master batch that combines both the excellent features for the purpose of better production efficiency.

Responding to this market need, both companies have, after having identified the effectiveness of these two agents in straight resins, decided to go into R&D for a new formulation. However in the process they found the liquid and powder components hard to mix and when compounded yielded a non-stable master batch. Hence, the R&D team diligently seeks ways to apply their emulsification technology and succeeded to breakthrough the technical obstacles.

During a performance test, the cultured medium was put to compare with set PVC sheets made with non-additive compounded agents, it was found that the latter showed bacterial growth all over the surface after 24 hours; whereas the cultured medium shows no sign of any live staphylococcus aureus as well as growth of mildew, algae, or chlorella such as malted rice mildew, penicillium notatum, even after 4 weeks.

Even though the domestic market for flexible PVC is generally shrinking due to environmental problem, but for application such as consumer goods and sundries a firm steady demand still exists because of cost consciousness as well as advantage in moldability. Nagase find this a business opportunity and plan to proactively grow sales in this market.

Nagase will first introduce this new master batch to the market with PVC master batch produced by this technology, and then target its application to flexible plastic moldings such as wallpaper, water-contacting products, film for agriculture, etc. Sales projection is estimated at 400 million to 500 million yen by the end of three years. Next, they are considering extending the sales to polyolefin market as they think there may be a possibility for conversion.

(Source: Nagase & Co. Ltd)

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